Some of the highlights to pay attention to, that is, if you can concentrate on what's going on over Smith's heavy breathing, lip-smacking and maniacal hand-rubbing:
1) Smith ogling the latest cover of GQ featuring a nekkid Aniston wearing nothing but a neck tie @ 1:13 in the video. He obviously loses complete interest in the interview for a second as he musters up every ounce of will power to keep his pants on.
2) @1:22 - Smith giving Aniston a bow tie to wear for her next cover shoot
3) @2:11 - Continuing with the interview's John Hinkley feel, Smith - leaning in WAY too close - begins a line of questioning that ends with the request of "take me into your life for just a second." Seems an innocuous enough question to ask a celebrity, but you get the feeling he meant to say, "take me into your life for just a second, because my infra-red goggles can only tell me so much. Specifically, tell me what I would see in your bedroom if it wasn't obstructed by those hedges."
4) @ 4:19 - "All right, baby" --- Seriously, at this point I hope Aniston is keeping an eye on her green tea. Smith slipping some roofies into her Early Show mug is not out of the question. I think I actually see a bottle of ether fall out of his jacket pocket and roll around, too.
5) @4:24 - Smith ends the first part of the interview with "you look great", then again loses concentration, trails off and makes some pervy under-the-breath "Mmm" noise/moan.
Enjoy.